You need to modify the document that you are printing from so that the printer knows what you want to do.
For example in MS Word you can navigate to File > Print > Page Setup. Select the Paper tab and choose the option to select a source for First Page and a different source for Other pages. You could also select a page and make the same change but with the Apply to: This page forward setting and alternate each page if you wanted.
These changes must be made on the document or application level. The print driver and printer are not going to be able to make those changes for you. Contact the application owners support team for confirmation on the various printer configuration options that are available if you need more assistance.